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Title Iminothioindoxyl as a molecular photoswitch with 100 nm band separation in the visible range Author info Mark W. H. Hoorens ... [et al.] Author Hoorens Mark W. H. (20%)
Co-authors Medveď Miroslav 1971- (10%) UMBFP08 - Katedra chémie
Laurent Adéle D. (10%)
Di Donato Mariangela (10%)
Fanetti Samuele (5%)
Slappendel Laura (5%)
Hilbers (5%)
Feringa Ben L. (10%)
Buma Wybren Jan (10%)
Szymański Wiktor (15%)
Source document Nature Communications. Vol. 10, no. 2390 (2019), pp. 1-11. - London : Nature Research, 2019 Keywords molekulové fotoprepínače - molecular photoswitches teória funkcionálu hustoty chémia - chemistry prírodné vedy - natural sciences fotochemické reakcie - photochemical reactions Form. Descr. články - journal articles Language English Country Great Britian Annotation Light is an exceptional external stimulus for establishing precise control over the properties and functions of chemical and biological systems, which is enabled through the use of molecular photoswitches. Ideal photoswitches are operated with visible light only, show large separation of absorption bands and are functional in various solvents including water, posing an unmet challenge. Here we show a class of fully-visible-light-operated molecular photoswitches, lminothioindoxyls (ITIs) that meet these requirements. ITIs show a band separation of over 100 nm, isomerize on picosecond time scale and thermally relax on millisecond time scale. Using a combination of advanced spectroscopic and computational techniques, we provide the rationale for the switching behavior of ITIs and the influence of structural modifications and environment, including aqueous solution, on their photochemical properties. This research paves the way for the development of improved photo-controlled systems for a Public work category ADC No. of Archival Copy 47137 Catal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Database xpca - PUBLIKAČNÁ ČINNOSŤ References PERIODIKÁ-Súborný záznam periodika Title Fotochémia Subtitle princípy a aplikácie Author info J. Šima ... [et al.] Author Šima Jozef
Issue data Bratislava : Slovenská technická univerzita , 2011. - 337 s. : sch., tab., 25 cm Issue 1. vyd. Edition Edícia vysokoškolských učebníc ISBN 978-80-227-3440-0 Note Bibliografia s. 319-326. Index Keywords fotochémia - photochemistry fotochemické reakcie - photochemical reactions Language Slovak Country Slovak Republic systematics 544.52 Catal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Database xkni - BOOKS Copy count 1, currently available 1 Call number Location Sublocation Umiestnenie Info 326587 Univerzita Mateja Bela Department of absent lending Title Molekulové reakce a fotochemie Author info Charles H. DePuy, Orville L. Chapman; Preklad: Miloš Nepraš Author DePuy Charles H.
Co-authors Chapman Orville L.
Another authors Nepraš Miloš (Translator)
Issue data Praha : SNTL - Nakladatelství technické literatury , 1978. - 192 s. : obr., reg., tab., 21 cm Issue 1. vyd. Note Bibliografia s. 184 Keywords organická chémia - organic chemistry molekulové reakcie fotochemické reakcie - photochemical reactions Language Czech Country Czechoslovakia systematics 547 Catal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Database xkni - BOOKS Copy count 2, currently available 1, at library only 1 Call number Location Sublocation Umiestnenie Info 120326 Univerzita Mateja Bela Department of absent lending 120325 Univerzita Mateja Bela Department of chemistry In-Library Use Only