Výsledky vyhľadávania
Názov Mechanistic insights into the photoisomerization of N,N′-disubstituted indigos Aut.údaje Šimon Budzák, Justina Jovaišaitė ... [et al.] Autor Budzák Šimon 1982- (15%) UMBFP08 - Katedra chémie
Spoluautori Jovaišaitė Justina (15%)
Huang Chung-Yang (15%)
Baronas Paulius (10%)
Tulaitė Kamilė (10%)
Juršėnas Saulius (10%)
Jacquemin Denis (10%)
Hecht Stefan (15%)
Zdroj.dok. Chemistry - A European Journal. Vol. 28, no. 26 (2022), pp. [1-9]. - Weinheim : Wiley-VCH, 2022 Kľúč.slová fotoprepínače - photoswitches počítačová chémia farbivá pigmenty Form.deskr. články - journal articles Jazyk dok. angličtina Krajina Nemecko URL Link na zdrojový dokument Kategória publikačnej činnosti ADC Číslo archívnej kópie 52655 Katal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Báza dát xpca - PUBLIKAČNÁ ČINNOSŤ Odkazy PERIODIKÁ-Súborný záznam periodika 
článok
Názov Highly cooperative photoswitching in dihydropyrene dimers Aut.údaje Pauline Liesfeld, Yves Garmshausen ... [et al.] Autor Liesfeld Pauline (16%)
Spoluautori Garmshausen Yves (14%)
Budzák Šimon 1982- (14%) UMBFP08 - Katedra chémie
Becker Jonas (14%)
Dallmann André (14%)
Jacquemin Denis (14%)
Hecht Stefan (14%)
Zdroj.dok. Angewandte Chemie : international edition. Vol. 59, no. 43 (2020), pp. 19352-19358. - Weinheim : John Wiley & Sons, 2020 Kľúč.slová analytická chémia - analytical chemistry koordinačné zlúčeniny kooperatívne spôsobilosti fotochromizmus - photochromism spektroskopia - spectroscopy fotochémia - photochemistry Form.deskr. články - journal articles Jazyk dok. angličtina Krajina Nemecko Anotácia We present a strategy to achieve highly cooperative photoswitching, where the initial switching event greatly facilitates subsequent switching of the neighboring unit. By linking donor/acceptor substituted dihydropyrenes via suitable pi-conjugated bridges, the quantum yield of the second photochemical ring-opening process could be enhanced by more than two orders of magnitude as compared to the first ring-opening. As a result, the intermediate mixed switching state is not detected during photoisomerization although it is formed during the thermal back reaction. Comparing the switching behavior of various dimers, both experimentally and computationally, helped to unravel the crucial role of the bridging moiety connecting both photochromic units. The presented dihydropyrene dimer serves as model system for longer cooperative switching chains, which, in principle, should enable efficient and directional transfer of information along a molecularly defined path. Moreover, our concept allows URL Link na zdrojový dokument Link do databázy Scopus Kategória publikačnej činnosti ADC Číslo archívnej kópie 49994 Kategória ohlasu LE BRAS, Laura - LEMARCHAND, Claire - ALOISE, Stephane - ADAMO, Carlo - PINEAU, Nicolas - PERRIER, Aurelie. Modeling photonastic materials : a first computational study. In Journal of chemical theory and computation. ISSN 1549-9618, 2020, vol. 16, no. 11, pp. 7017-7032.
GHOSH, Sanjib - HOSSAIN, Munshi Sahid - CHATTERJEE, Sheelbhadra - RAHAMAN, Sk Atiur - BANDYOPADHYAY, Subhajit. Light-gated modulation of electronic mobility of a dihydropyrene-based photochromic coordination polymer. In ACS applied materials and interfaces. ISSN 1944-8244, 2020, vol. 12, no. 47, pp. 52983-52991.
LVOV, Andrey G. - BREDIHHIN, Aleksei. Azulene as an ingredient for visible-light- and stimuli-responsive photoswitches. In Organic and biomolecular chemistry. ISSN 1477-0520, 2021, vol. 19, no. 20, pp. 4460-4468.
Katal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Báza dát xpca - PUBLIKAČNÁ ČINNOSŤ Odkazy PERIODIKÁ-Súborný záznam periodika článok
Názov Efficient light-induced pK(a) modulation coupled to base-catalyzed photochromism Aut.údaje Johannes Gurke ... [et al.] Autor Gurke Johannes (20%)
Spoluautori Budzák Šimon 1982- (20%) UMBFP08 - Katedra chémie
Schmidt Bernd M. (20%)
Jacquemin Denis (20%)
Hecht Stefan (20%)
Zdroj.dok. Angewandte Chemie : international edition : a journal of the German Chemical Society. Vol. 57, no. 17 (2018), pp. 4797-4801. - Weinheim : Wiley-VCH, 2018 Kľúč.slová fotoprepínače - photoswitches acidity aromaticity diarylethenes fotochromizmus - photochromism Jazyk dok. angličtina Krajina Nemecko Systematika 54 Anotácia Photoswitchable acid-base pairs, whose pK(a) values can be reversibly altered, are attractive molecular tools to control chemical and biological processes with light. A significant, light-induced pK(a) change of three units in aqueous medium has been realized for two thermally stable states, which can be interconverted using UV and green light. The light-induced pK(a) modulation is based on incorporating a 3-H-thiazol-2-one moiety into the framework of a diarylethene photoswitch, which loses the heteroaromatic stabilization of the negatively charged conjugate base upon photochemical ring closure, and hence becomes significantly less acidic. In addition, the efficiency of the photoreactions is drastically increased in the deprotonated state, giving rise to catalytically enhanced photochromism. It appears that protonation has a significant influence on the shape of the ground- and excited-state potential energy surfaces, as indicated by quantum-chemical calculations. Kategória publikačnej činnosti ADC Číslo archívnej kópie 43297 Kategória ohlasu LVOV, Andrey G. - KHUSNIYAROV, Marat M. - SHIRINIAN, Valerii Z. Azole-based diarylethenes as the next step towards advanced photochromic materials. In Journal of photochemistry and photobiology C : photochemistry reviews. ISSN 1389-5567, 2018, vol. 36, pp. 1-23.
KOEPPE, Benjamin - RUEHL, Steffen - ROEMPP, Florian. Towards more effective, reversible pH control by visible light alone : a thioindigo photoswitch undergoing a strong pK(a) modulation by isomer-specific hydrogen bonding. In ChemPhotoChem. ISSN 2367-0932, 2019, vol. 3, no. 2, pp. 71-74.
NIHEI, Masayuki - YANAI, Yuta - NATKE, Dominik - TAKAYAMA, Ryo - KATO, Marina - SEKINE, Yoshihiro - RENZ, Franz - OSHIO, Hiroki. Solid-state hydrogen-bond alterations in a [Co2Fe2] complex with bifunctional hydrogen-bonding donors. In CHemistry - a European journal. ISSN 0947-6539, 2019, vol. 25, no. 31, pp. 7449-7452.
GOLE, Bappaditya - KAUFFMANN, Brice - MAURIZOT, Victor - HUC, Ivan - FERRAND, Yann. Light-controlled conformational switch of an aromatic oligoamide foldamer. In Angewandte Chemie : international edition. ISSN 1433-7851, 2019, vol. 58, no. 24, pp. 8063-8067.
PARSONS, Drew F. - SALIS, Andrea. A thermodynamic correction to the theory of competitive chemisorption of ions at surface sites with nonelectrostatic physisorption. In Journal of chemical physics. ISSN 0021-9606, 2019, vol. 151, no. 2.
LIU, Di - SPONZA, Alvaro D. - YANG, Dandan - CHIU, Melanie. Modulating polymer dispersity with light : cationic polymerization of vinyl ethers using photochromic initiators. In Angewandte Chemie : international edition. ISSN 1433-7851, 2019, vol. 58, no. 45, pp. 16210-16216.
AMOUROUX, Baptiste - ROUX, Clement - MICHEAU, Jean-Claude - GAUFFRE, Fabienne - COUDRET, Christophe. A photochemical determination of luminescence efficiency of upconverting nanoparticles. In Beilstein journal of organic chemistry. ISSN 1860-5397, 2019, vol. 15, pp. 2671-2677.
MIZUTSU, Ryo - ASATO, Ryosuke - MARTIN, Colin J. - YAMADA, Mihoko - NISHIKAWA, Yoshiko - KATAO, Shohei - YAMADA, Miku - NAKASHIMA, Takuya - KAWAI, Tsuyoshi. Photo-Lewis acid generator based on radical-free 6 pi photo-cyclization reaction. In Journal of the American chemical society. ISSN 0002-7863, 2019, vol. 141, no. 51, pp. 20043-20047.
LVOV, Andrey G. - YADYKOV, Anton V. - LYSSENKO, Konstantin A. - HEINEMANN, Frank W. - SHIRINIAN, Valerii Z. - KHUSNIYAROV, Marat M. Reversible shifting of a chemical equilibrium by light : the case of keto-enol tautomerism of a beta-ketoester. In Organic letters. ISSN 1523-7060, 2020, vol. 22, no. 2, pp. 604-609.
BERTON, Cesare - BUSIELLO, Daniel Maria - ZAMUNER, Stefano - SOLARI, Euro - SCOPELLITI, Rosario - FADAEI-TIRANI, Farzaneh - SEVERIN, Kay - PEZZATO, Cristian. Thermodynamics and kinetics of protonated merocyanine photoacids in water. In Chemical science. ISSN 2041-6520, 2020, vol. 11, no. 32, pp. 8457-8468.
LUDWIG, Jannis - HELBERG, Julian - ZIPSE, Hendrik - HERGES, Rainer. Azo-dimethylaminopyridine-functionalized Ni(II)-porphyrin as a photoswitchable nucleophilic catalyst. In Beilstein journal of organic chemistry. ISSN 1860-5397, 2020, vol. 16, pp. 2119-2126.
KAISER, Christoph - HALBRITTER, Thomas - HECKEL, Alexander - WACHTVEITL, Josef. Proton-transfer dynamics of photoacidic merocyanines in aqueous solution. In Chemistry - a European journal. ISSN 0947-6539, 2021, vol. 27, no. 35, pp. 9160-9173.
Katal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Báza dát xpca - PUBLIKAČNÁ ČINNOSŤ Odkazy PERIODIKÁ-Súborný záznam periodika 
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